1. Which statement best describes a sigma (σ) bond?
2. In an ethene molecule (C2H4), how many sigma (σ) bonds and pi (π) bonds are present between the two carbon atoms in the molecule?
3. Which atomic orbitals can form a sigma (σ) bond through head-on overlap?
4. A pi (π) bond is found in molecules such as ethene and propene and is formed by the sideways overlap of -orbitals. The bond strength of a pi (π) bond compared to sigma (σ) bonds shows that a pi (π) bond is much than a sigma (σ) bond.
5. What is a key characteristic of the electron density in a pi (π) bond?
6. What is the meaning of the term "delocalised electrons"?
7. Resonance theory is used to describe molecules where:
8. Which of the following molecules show resonance?
9. In resonance structures the move between different contributing forms but the remain in fixed positions and do not move.
10. How many pi (π) electrons are delocalised in a benzene molecule?
a) 2 b) 4 c) 6 d) 8
11. In the circle notation used to represent the benzene molecule what does the circle represent?
a) The fixed positions of the pi electrons within the ring b) The presence of alternating single and double bonds c) The delocalisation of the six pi (π) electrons in the benzene ring d) The restricted rotation around the carbon-carbon bonds
12. What is the main reason that benzene cannot be accurately drawn using a single structure?
a) It has too many atoms b) Some of its bonding electrons are delocalised c) Its bonds are constantly breaking and reforming d) It is an unstable molecule
13. Why are aromatic amines such as like phenylamine (aniline) poorer bases compared to aliphatic amines?
a) They are less soluble in water b) They generally have more carbon atoms than aliphatic amines c) Their nitrogen atom forms fewer bonds in aliphatic amines due to the presence of the benzene ring in aromatic amines d) The lone pair of electrons on the nitrogen atom is delocalised into the aromatic ring
14. Which of the following statements is true?
a) Resonance involves the movement of both electrons and atomic nuclei b) The more resonance structures that can be drawn, the less stable a molecule will be. c) The overall actual structure of a molecule is a hybrid or composite of all individual resonance structures. d) Resonance only occurs in simple molecules like methane
15. Ozone (O3) is a small molecule which undergoes resonance. Which of the following statements is true about the bonding in ozone?
a) One bond is a single bond and the other is a double covalent bond b) Both bonds present between the oxygen atoms are single covalent bonds c) Both bonds present between the oxygen atoms are double covalent bonds d) Both bonds are identical and intermediate in length between a single and a double bond